AssayIndex
Cross-section

Humanin (HNG) impurity profile

Every named species the index has reported alongside Humanin (HNG), how often, at what level, and what its presence implies about the synthesis or the handling. Reporting threshold is 0.05 % area; anything below it is invisible to this page and is silently added to the main peak.

42 recordsmedian 99.47 %spec 97.5 %
Median total impurities 0.54% n=42
Median largest single 0.34% n=42
Worst single observed 1.59% n=42
Named species observed 4 / 4 n=4
Named speciesΔRT (min)Δ mass (Da)Seen inMedian % areaMax % area
wild-type humanin (Ser14, −42 Da)-0.15-42.011100%0.100.95
deamidated (+1 Da)-0.28+0.98488%0.121.17
truncated (1-20)-1.35-472.24588%0.110.89
Met sulfoxide (+16 Da)-0.42+15.99586%0.071.59

wild-type humanin (Ser14, −42 Da)

Retention offset from the main peak
-0.15 min on RG-2
Mass difference
-42.011 Da
Reported in
42 of 42 records (100 %)
Level when reported
median 0.10 %, max 0.95 %
Resolution requirement
Close-eluting — resolution below 1.2 is common and the peaks merge on short gradients.

deamidated (+1 Da)

Retention offset from the main peak
-0.28 min on RG-2
Mass difference
+0.984 Da
Reported in
37 of 42 records (88 %)
Level when reported
median 0.12 %, max 1.17 %
Resolution requirement
Close-eluting — resolution below 1.2 is common and the peaks merge on short gradients.

truncated (1-20)

Retention offset from the main peak
-1.35 min on RG-2
Mass difference
-472.245 Da
Reported in
37 of 42 records (88 %)
Level when reported
median 0.11 %, max 0.89 %
Resolution requirement
Baseline-resolved on the reference method.

Met sulfoxide (+16 Da)

Retention offset from the main peak
-0.42 min on RG-2
Mass difference
+15.995 Da
Reported in
36 of 42 records (86 %)
Level when reported
median 0.07 %, max 1.59 %
Resolution requirement
Baseline-resolved on the reference method.

Degradation pathways

Degradants are a handling finding rather than a synthesis finding. A lot that shipped clean and arrived oxidised tells you about the courier, not the chemist.

  • Met oxidation
  • aggregation above 1 mg/mL in neutral buffer